Modi departed for Poland on Wednesday and will visit Kyiv on Friday, the first trip to Ukraine by an Indian prime minister since diplomatic relations were established more than three decades back,
Reuters reported.
"I look forward to the opportunity to ... share perspectives on peaceful resolution of the ongoing Ukraine conflict," Modi said in a statement on Wednesday before his departure. "As a friend and partner, we hope for an early return of peace and stability in the region."
India and Russia have been close friends since the days of the Soviet Union and New Delhi has not condemned Moscow's invasion of Ukraine, instead urging both sides to use dialogue and diplomacy to resolve their differences.
Russia became India's top oil supplier since the war began as Indian refiners snapped up cheap Russian crude.
New Delhi has also remained engaged with Kyiv, with Modi meeting Zelenskiy on the sidelines of the Group of Seven summit in Italy in June. They have also spoken several times by phone.